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石墨烯的制備、性質、應用與展望 版權信息
- ISBN：9787302556213
- 條形碼：9787302556213 ; 978-7-302-55621-3
- 裝幀：一般膠版紙
- 冊數：暫無
- 重量：暫無
- 所屬分類：>>
石墨烯的制備、性質、應用與展望 本書特色
石墨烯是從石墨中提取的一種新型碳材料，具有非同尋常的機械性能和物理性能。本書從材料制備、性能評價、各種開發和應用技術等方面詳細討論了這種新型材料的研究進展，探討了這種材料的發展前景和技術路徑。本書非常適合高校和科研院所材料科學及物理、電子等專業的師生及生產企業的工程技術人員閱讀參考。 國內外頂級專業人員的傾情奉獻，令讀者腦洞智力大開的熱門讀物國內外頂級專業人員的傾情奉獻，令讀者腦洞智力大開的熱門讀物
石墨烯的制備、性質、應用與展望 內容簡介
石墨烯是一種新型碳材料, 具有非同尋常的機械性能和物理性能。本書從材料制備、性能評價、各種開發和應用技術等方面詳細討論了這種新型材料的研究情況, 并探討了這種材料的發展前景和技術路徑。
石墨烯的制備、性質、應用與展望 目錄
Contents
Preface .............................................................................................................v
Acknowledgments ..............................................................................................vii
Chapter 1: Introduction......................................................................................1
1.1 What is graphene?.................................................................................................. 1
1.2 Fundamentals of materials science for carbon materials ..................................... 5
1.2.1 Classi.cation of carbon materials ..................................................................... 5
1.2.2 Structure and nanotexture of carbon materials.................................................6
1.2.3 Carbonization and graphitization ...................................................................... 8
1.2.4 Carbon materials .............................................................................................. 12
1.3 Construction and purposes of the current book..................................................29
References................................................................................................................... 31
Chapter 2: Preparation of graphene .................................................................. 39
2.1 Chemical vapor deposition .................................................................................. 41
2.1.1 Synthesis of graphene .lms............................................................................. 41
2.1.2 Synthesis of graphene .akes ........................................................................... 60
2.1.3 Synthesis of single-walled carbon nanohorns.................................................65
2.1.4 Substitutional doping of heteroatoms.............................................................. 69
2.1.5 Graphene foams ............................................................................................... 80
2.2 Cleavage (peeling) ............................................................................................... 81
2.2.1 Mechanical cleavage........................................................................................81
2.2.2 Cleavage in solution ........................................................................................ 85
2.2.3 Cleavage via intercalation compounds............................................................95
2.3 Exfoliation via graphene oxide.......................................................................... 101
2.3.1 Synthesis of graphene oxide..........................................................................102
2.3.2 Exfoliation of graphene oxide ....................................................................... 105
2.3.3 Reduction of graphene oxide......................................................................... 107
2.3.4 Fabrication of reduced graphene oxide foams (sponges).............................123
2.3.5 Functionalization of reduced graphene oxide...............................................127
2.3.6 Substitutional doping of heteroatoms............................................................ 133
2.3.7 Fabrication of transparent reduced graphene oxide .lms ............................ 135
2.4 Other processes .................................................................................................. 138
2.4.1 Chemical synthesis......................................................................................... 138
i
Contents
2.4.2 Synthesis via pyrolysis .................................................................................. 143
2.4.3 Unzipping of carbon nanotubes..................................................................... 147
2.5 Concluding remarks ........................................................................................... 150
References................................................................................................................. 153
Chapter 3: Electrical properties and applications .............................................. 173
3.1 Fundamental electrical properties...................................................................... 174
3.1.1 Electronic structure of graphene ................................................................... 174
3.1.2 Effects of defects and edges..........................................................................181
3.2 Applications to information technology............................................................189
3.2.1 Transistor devices........................................................................................... 189
3.2.2 Spintronics devices ........................................................................................ 207
3.2.3 Transparent electrode.....................................................................................221
3.3 Applications to social .elds .............................................................................. 226
3.3.1 Sensor devices................................................................................................226
3.3.2 Photon detectors.............................................................................................233
3.3.3 Resistance standard........................................................................................237
3.3.4 Electron .eld emission .................................................................................. 242
3.4 Concluding remarks ........................................................................................... 244
References................................................................................................................. 244
Chapter 4: Chemical properties and applications............................................... 251
4.1 Fundamental chemical properties......................................................................252
4.1.1 Hydrogenation................................................................................................253
4.1.2 Oxygenation ................................................................................................... 256
4.1.3 Layer modi.cation.........................................................................................258
4.2 Applications to energy storage and conversion ................................................ 259
4.2.1 Lithium-ion batteries...................................................................................... 259
4.2.2 Electrochemical capacitors ............................................................................ 268
4.2.3 Lithium-ion capacitors...................................................................................278
4.2.4 Lithium-sulfur batteries ................................................................................. 282
4.2.5 Solar cells (photovoltaic cells) ...................................................................... 292
4.2.6 Fuel cells ........................................................................................................ 298
4.2.7 Hydrogen storage ........................................................................................... 306
4.3 Applications to environment remediation ......................................................... 311
4.3.1 Adsorption of polluting molecules and ions.................................................311
4.3.2 Sorption and recovery of oils ........................................................................ 321
4.3.3 Capacitive deionization for water desalination.............................................325
4.3.4 Catalysts ......................................................................................................... 332
4.3.5 Chemical sensors............................................................................................ 341
4.4 Concluding remarks ........................................................................................... 352
References................................................................................................................. 354
ii
Contents
Chapter 5: Mechanical properties and applications............................................ 373
5.1 Fundamental mechanical properties .................................................................. 374
5.2 Nanolubricants.................................................................................................... 383
5.3 Mechanical sensors ............................................................................................ 387
5.4 Mechanical reinforcement ................................................................................. 393
5.4.1 Reinforcement of plastics .............................................................................. 393
5.4.2 Reinforcement of ceramics............................................................................395
5.4.3 Reinforcement of metals................................................................................ 400
5.5 Reduced graphene oxide .bers.......................................................................... 404
5.6 Concluding remarks ........................................................................................... 409
References................................................................................................................. 410
Chapter 6: Thermal properties and applications................................................ 415
6.1 Fundamental thermal properties ........................................................................ 416
6.2 Thermal interface materials ............................................................................... 422
6.3 Nano.uids........................................................................................................... 429
6.4 Thermoelectric power ........................................................................................ 432
6.5 Thermal energy storage ..................................................................................... 436
6.6 Concluding remarks ........................................................................................... 442
References................................................................................................................. 443
Chapter 7: Biomedical properties and applications ............................................ 449
7.1 Biocompatibility.................................................................................................450
7.2 Cell management................................................................................................ 454
7.2.1 Scaffolds for cell culturing ............................................................................ 454
7.2.2 Stem cell differentiation ................................................................................ 458
7.2.3 Cell imaging...................................................................................................459
7.2.4 Antibacterial activity...................................................................................... 460
7.3 Drug delivery systems........................................................................................ 464
7.4 Biosensors........................................................................................................... 469
7.5 Concluding remarks ........................................................................................... 476
References................................................................................................................. 478
Chapter 8: Beyond graphene........................................................................... 485
8.1 Graphene derivatives..........................................................................................486
8.1.1 Graphane (hydrogenated graphene)............................................................... 487
8.1.2 Fluorographene (.uorinated graphene) ......................................................... 495
8.1.3 Graphene oxide (oxidized graphene) ............................................................ 501
8.1.4 Graphyne and graphdiyne..............................................................................514
8.2 Single-layer materials ........................................................................................ 519
8.2.1 Honeycomb layers of group IV elements...................................................... 519
8.2.2 Honeycomb layers of group IIIeV compounds ........................................... 524
8.2.3 Single layers of transition metal dichalcogenides ........................................ 531
iii
Contents
8.3 Layer-by-layer composites................................................................................. 537
8.4 Concluding remarks ........................................................................................... 544
References................................................................................................................. 546
Chapter 9: Summary and prospects.................................................................561
9.1 Summary on graphene ....................................................................................... 561
9.2 Prospects.............................................................................................................565
9.2.1 Importance of number of layers stacked..................................................... 565
9.2.2 Two kinds of graphene materials ................................................................ 570
9.2.3 Field effect and zero bandgap ..................................................................... 572
9.2.4 Extremely high thermal conductivity..........................................................574
9.2.5 Basics for molecular sensing.......................................................................576
9.2.6 Basics for foreign atom doping...................................................................578
9.2.7 Importance of pep interaction................................................................... 580
9.2.8 Biomedical applications............................................................................... 582
9.2.9 New composite materials............................................................................. 585
9.2.10 Extension to organic chemistry ................................................................... 588
References................................................................................................................. 589
Index ............................................................................................................ 593
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石墨烯的制備、性質、應用與展望 作者簡介
The authors of this book are composed of two persons who have been working on carbon materials, published many research papers and recently published three books on carbon materials on their fundamentals, advances and characterizations (M. Inagaki and F. Kang) and two persons who have been working on graphene from the standpoints of physics (K. Takai), and biochemical applications (S. Tsujimura). The book is going to be written under the corporation of four authors by sharing the responsibilities on whole
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