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鈣鈦礦氧化物中的結構——性質關聯 版權信息
- ISBN：9787566719331
- 條形碼：9787566719331 ; 978-7-5667-1933-1
- 裝幀：一般膠版紙
- 冊數：暫無
- 重量：暫無
- 所屬分類：>
鈣鈦礦氧化物中的結構——性質關聯 內容簡介
本書主要討論對于鈣鈦礦氧化物晶格自由度的調控, 以及鈣鈦礦氧化物薄膜材料中晶體結構與物理性質的關聯。作者通過氧化物薄膜外延生長以及國際*前沿的晶體結構表征技術, 實現了對晶格自由度中的眾多結構特性 (包括晶格的延展與壓縮, 晶格的單向傾斜, 氧八面體旋轉, 表面晶格結構) 的有效以及定量的調控。
鈣鈦礦氧化物中的結構——性質關聯 目錄
List of Figures
List of Tables
List of Symbols and Abbreviations
1 Structure-property coupling in perovskite oxides
1．1 Introduction to perovskite oxides
1．2 Lattice degree of freedom and structural features
1．3 Motivation and opportunities
1．4 Statement and organization of the dissertation
2 The control and manipulation of perovskite structures
2．1 An epitaxial thin-film approach
2．2 Control of lattice structures in perovskite thin films
2．3 Control of surface structures in perovskite thin films
3 Characterization of perovskite heterostructures
3．1 Structural characterization of perovskite oxides
3．2 Physical properties and characterization
4 Structure control，magnetism，and transport in SrRuO
4．1 Introduction
4．2 Sample design and thin-film synthesis
4．3 Structural characterization
4．4 Octahedra rotational domains
4．5 Impact on physical properties of SrRuOs
4．6 Conclusions
5 Control of antiferro-/ferroelectricity in PbZrO3
5．1 Introduction
5．2 PbZrO，thin-film growth dynamics
5．3 Structural and chemistry characterization
5．4 Electrical characterization
5．5 Lattice symmetry determination
5．6 Energy ground states in lead-excess PbZrOs
5．7 Conclusions
6 Designing optimal ion-conducting perovskite structure
6．1 Introduction
6．2 Strain engineering and quantification of structural features
6．3 Ion-transport measurement
6．4 First-principle calculations
6．5 Experimental realization of the optimal structure
6．6 Conductivity measurement in superlatice structures
6．7 Conclusions
7 Correlating surface orientations and electrochemistry
7．1 Introduction
7．2 Epitaxial all-perovskite，half-cell structures
7．3 Heterostructure synthesis and characterization of the half-cels
7．4 The fabrication of the epitaxial half cells
7．5 Validating the epitaxial half cells
7．6 Orientation-dependent gas-exchange kinetics
7．7 Rate-limiting step in the gas exchange reactions
7．8 Conclusions and future works
8 Summary of findings and suggestions
8．1 Summary of findings
8．2 Suggestions for future work
References
Appendix A Pseudo-cubic lattice notation
Appendix B Characterization of thin-film chemistry
B．1 Rutherford backscattering spectrometry
B．2 X-ray photoelectron spectroscopy
B．3 Low-energy ion scattering spectroscopy
Appendix C Electrochemical impedance spectroscopy
C．1 Ionic diffusion in mixed conductors
C．2 Surface reaction at solid-gas interface
Acknowledgments
List of Tables
List of Symbols and Abbreviations
1 Structure-property coupling in perovskite oxides
1．1 Introduction to perovskite oxides
1．2 Lattice degree of freedom and structural features
1．3 Motivation and opportunities
1．4 Statement and organization of the dissertation
2 The control and manipulation of perovskite structures
2．1 An epitaxial thin-film approach
2．2 Control of lattice structures in perovskite thin films
2．3 Control of surface structures in perovskite thin films
3 Characterization of perovskite heterostructures
3．1 Structural characterization of perovskite oxides
3．2 Physical properties and characterization
4 Structure control，magnetism，and transport in SrRuO
4．1 Introduction
4．2 Sample design and thin-film synthesis
4．3 Structural characterization
4．4 Octahedra rotational domains
4．5 Impact on physical properties of SrRuOs
4．6 Conclusions
5 Control of antiferro-/ferroelectricity in PbZrO3
5．1 Introduction
5．2 PbZrO，thin-film growth dynamics
5．3 Structural and chemistry characterization
5．4 Electrical characterization
5．5 Lattice symmetry determination
5．6 Energy ground states in lead-excess PbZrOs
5．7 Conclusions
6 Designing optimal ion-conducting perovskite structure
6．1 Introduction
6．2 Strain engineering and quantification of structural features
6．3 Ion-transport measurement
6．4 First-principle calculations
6．5 Experimental realization of the optimal structure
6．6 Conductivity measurement in superlatice structures
6．7 Conclusions
7 Correlating surface orientations and electrochemistry
7．1 Introduction
7．2 Epitaxial all-perovskite，half-cell structures
7．3 Heterostructure synthesis and characterization of the half-cels
7．4 The fabrication of the epitaxial half cells
7．5 Validating the epitaxial half cells
7．6 Orientation-dependent gas-exchange kinetics
7．7 Rate-limiting step in the gas exchange reactions
7．8 Conclusions and future works
8 Summary of findings and suggestions
8．1 Summary of findings
8．2 Suggestions for future work
References
Appendix A Pseudo-cubic lattice notation
Appendix B Characterization of thin-film chemistry
B．1 Rutherford backscattering spectrometry
B．2 X-ray photoelectron spectroscopy
B．3 Low-energy ion scattering spectroscopy
Appendix C Electrochemical impedance spectroscopy
C．1 Ionic diffusion in mixed conductors
C．2 Surface reaction at solid-gas interface
Acknowledgments
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鈣鈦礦氧化物中的結構——性質關聯 作者簡介
高然，男，現任職于阿里巴巴達摩院，美國加利福尼亞大學伯克利分校材料科學與工程系博士畢業，2015-2019年，師從美國功能氧化物薄膜專家Lane W.Martin 教授，專攻氧化物外延薄膜的生長、結構調控、以及薄膜性能研究，其研究論文發表于世界材料科學期刊如Nature Materials,Advanced Materials, Nature Communication,Chemistry of Materials 等，發表SCI一區論文20余篇。他多次參與美國材料科學協會與美國物理協會會議并發表演講。
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