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REACTION ENGINEERING(反應工程) 版權信息
- ISBN：9787122306722
- 條形碼：9787122306722 ; 978-7-122-30672-2
- 裝幀：一般膠版紙
- 冊數：暫無
- 重量：暫無
- 所屬分類：>
REACTION ENGINEERING(反應工程) 內容簡介
本書立足于傳授反應工程基本原理，并與工程實踐相結合；服務于高等院；ゎ悓I的廣大師生，工程公司的設計人員以及生產企業的工程技術人員。 內容編排采用了循序漸進的方式。首先，分別介紹氣固相催化反應的本征和宏觀動力學，推導了間歇反應器、全混流反應器和活塞流反應器三種理想反應器的設計方程；在連續反應器流動模型的基礎之上，建立起固定床、流化床和流固相非催化反應動力學及真實反應器的模型；同時，將反應器的間歇與連續、恒容與變容、絕熱與換熱的各種操作方式貫穿其中，并簡要介紹了操作過程的多定態和定態穩定性；很后，針對生化、聚合及電化學反應工程的特點，分章加以介紹。全書共計13章，前7章可用作本科生教材，后6章可作為研究生的學習內容。 全書文字敘述精煉、模型推導詳盡、知識內容完整，并結合大量的例題和習題，深入淺出地傳授反應工程知識，培養讀者建立反應器模型和與之相關的工程設計能力。
REACTION ENGINEERING(反應工程) 目錄
List of Contributors xiii
Preface xv
1. Introduction 1
1.1 Chemical Reaction Engineering 1
1.2 Conversion and Yield of Chemical Reactions 4
1.2.1 Extent of Reaction 4
1.2.2 Conversion 5
1.2.3 Yield and Selectivity 7
1.3 Classifications of Chemical Reactors 10
1.4 Operation Modes of Chemical Reactors 13
1.5 Models in Reactor Design 16
1.6 Scale-Up of Industrial Reactors 19
Further Reading 22
Problems 22
2. Fundamentals of Reaction Kinetics 25
2.1 Reaction Rate 26
2.2 Reaction Rate Equations 30
2.3 Effect of Temperature on Reaction Rate 37
2.4 Multiple Reactions 44
2.4.1 Consumption Rate and Formation Rate 44
2.4.2 Basic Types of Multiple Reactions 45
2.4.3 Reaction Network 50
2.5 Transformation and Integration of Reaction Rate Equations 52
2.5.1 Single Reaction 52
2.5.2 Multiple Reactions 57
2.6 Heterogeneous Catalysis and Adsorption 60
2.6.1 Heterogeneous Catalysis 61
2.6.2 Adsorption and Desorption 62
2.7 Kinetics of Heterogeneous Catalytic Reactions 67
2.7.1 Steady-State Approximation and Rate-Determining Step 68
2.7.2 Rate Equations of Heterogeneous Catalytic Reactions 70
2.8 Determination of Kinetic Parameters 77
2.8.1 Integration Method 77
2.8.2 Differential Method 79
2.9 Procedure for Developing Reaction Rate Equation 86
Further Reading 87
Problems 88
3. Tank Reactor 95
3.1 Mass Balance for Tank Reactor 96
3.2 Design of Isothermal Batch Tank Reactor(Single Reaction) 97
3.2.1 Calculation of Reaction Time and Reaction Volume 98
3.2.2 Optimal Reaction Time 102
3.3 Design of Isothermal Batch Tank Reactor (Multiple Reactions) 103
3.3.1 Parallel Reactions 103
3.3.2 Consecutive Reactions 107
3.4 Reactor Volume for Continuous Tank Reactor (CSTR) 111
3.5 CSTR in Series and Parallel 115
3.5.1 Overview 115
3.5.2 Calculations for Multiple Reactors in Series 117
3.5.3 Optimal Reaction Volume Ratio for CSTR in Series 122
3.6 Yield and Selectivity for Multiple Reactions in a Tank Reactor 123
3.6.1 Overall Yield and Overall Selectivity 124
3.6.2 Parallel Reactions 125
3.6.3 Consecutive Reactions 129
3.7 Semibatch Tank Reactor 133
3.8 Nonisothermal Batch Reactor 138
3.9 Steady-State Operation of CSTR 145
3.9.1 Heat Balance for CSTR 145
3.9.2 Steady-States of CSTR 147
Summary 151
Further Reading 152
Problems 153
4. Tubular Reactor 161
4.1 Plug Flow 161
4.2 Design of Isothermal Tubular Reactor 163
4.2.1 Single Reaction 164
4.2.2 Multiple Reactions 168
4.2.3 Pseudo Homogeneous Model 176
4.3 Comparison of Reactor Volumes of Tubular and Tank Reactors 178
4.4 Recycle Reactor 184
4.5 Nonisothermal Tubular Reactor 185
4.5.1 Heat Balance Equation for Tubular Reactor 186
4.5.2 Adiabatic Tubular Reactor 188
4.5.3 Nonadiabatic Nonisothermal Tubular Reactor 193
4.6 Optimal Temperature Sequence for Tubular Reactors 197
4.6.1 Single Reaction 198
4.6.2 Multiple Reactions 200
Further Reading 203
Problems 203
5. Residence Time Distribution and Flow Models for Reactors 213
5.1 Residence Time Distribution 214
5.1.1 Overview 214
5.1.2 Quantitative Delineation of RTD 215
5.2 Experimental Determination of RTD 218
5.2.1 Pulse Experiments 219
5.2.2 Step Experiments 221
5.3 Statistical Eigenvalues of RTD 224
5.4 RTD of Ideal Reactors 228
5.4.1 Plug-Flow Model 228
5.4.2 Perfectly-Mixed Flow Model 230
5.5 Nonideal Flow Phenomenon 234
5.6 Nonideal Flow Models 238
5.6.1 Segregation Model 238
5.6.2 Tanks-in-Series Model 242
5.6.3 Axial Dispersion Model 247
5.7 Design of Nonideal Reactors 251
5.8 Mixing of Fluids in Flow Reactors 256
Further Reading 260
Problems 261
6. Chemical Reaction and Transport Phenomena in Heterogeneous System 265
6.1 Steps in Heterogeneous Reactions 266
6.1.1 Macroscopic Structures and Properties of Solid Catalyst Particles 266
6.1.2 Steps in a Catalytic Reaction 269
6.2 Heat and Mass Transfer Between Bulk Fluid and the Catalyst External Surface 270
6.2.1 Transport Coefficient 270
6.2.2 Concentration and Temperature Difference Between the External Surface of Catalyst and Bulk Fluid 272
6.2.3 Effect of External Diffusion on Heterogeneous Catalytic Reactions 275
6.3 Gas Diffusion in Porous Media 279
6.3.1 Diffusion in Pores 279
6.3.2 Diffusion in Porous Particles 280
6.4 Diffusion and Reaction in Porous Catalysts 281
6.4.1 Reactant Concentration Profile in Porous Catalysts 282
6.4.2 Internal Effectiveness Factor 285
6.4.3 Internal Effectiveness Factor for Non-first Order Reactions 290
6.4.4 Effectiveness Factor Under the Influences of Both Internal and External Diffusions 292
6.5 Effect of Internal Diffusion on Selectivity of Multiple Reactions 294
6.6 Determination of Diffusion Impact on Heterogeneous Reactions 297
6.6.1 Determination of the Effects of External Diffusion 297
6.6.2 Determining the Effects of Internal Diffusion 299
6.7 Effects of Diffusion on Experimental Measurement of Reaction Rate 301
Further Reading 305
Problems 306
Preface xv
1. Introduction 1
1.1 Chemical Reaction Engineering 1
1.2 Conversion and Yield of Chemical Reactions 4
1.2.1 Extent of Reaction 4
1.2.2 Conversion 5
1.2.3 Yield and Selectivity 7
1.3 Classifications of Chemical Reactors 10
1.4 Operation Modes of Chemical Reactors 13
1.5 Models in Reactor Design 16
1.6 Scale-Up of Industrial Reactors 19
Further Reading 22
Problems 22
2. Fundamentals of Reaction Kinetics 25
2.1 Reaction Rate 26
2.2 Reaction Rate Equations 30
2.3 Effect of Temperature on Reaction Rate 37
2.4 Multiple Reactions 44
2.4.1 Consumption Rate and Formation Rate 44
2.4.2 Basic Types of Multiple Reactions 45
2.4.3 Reaction Network 50
2.5 Transformation and Integration of Reaction Rate Equations 52
2.5.1 Single Reaction 52
2.5.2 Multiple Reactions 57
2.6 Heterogeneous Catalysis and Adsorption 60
2.6.1 Heterogeneous Catalysis 61
2.6.2 Adsorption and Desorption 62
2.7 Kinetics of Heterogeneous Catalytic Reactions 67
2.7.1 Steady-State Approximation and Rate-Determining Step 68
2.7.2 Rate Equations of Heterogeneous Catalytic Reactions 70
2.8 Determination of Kinetic Parameters 77
2.8.1 Integration Method 77
2.8.2 Differential Method 79
2.9 Procedure for Developing Reaction Rate Equation 86
Further Reading 87
Problems 88
3. Tank Reactor 95
3.1 Mass Balance for Tank Reactor 96
3.2 Design of Isothermal Batch Tank Reactor(Single Reaction) 97
3.2.1 Calculation of Reaction Time and Reaction Volume 98
3.2.2 Optimal Reaction Time 102
3.3 Design of Isothermal Batch Tank Reactor (Multiple Reactions) 103
3.3.1 Parallel Reactions 103
3.3.2 Consecutive Reactions 107
3.4 Reactor Volume for Continuous Tank Reactor (CSTR) 111
3.5 CSTR in Series and Parallel 115
3.5.1 Overview 115
3.5.2 Calculations for Multiple Reactors in Series 117
3.5.3 Optimal Reaction Volume Ratio for CSTR in Series 122
3.6 Yield and Selectivity for Multiple Reactions in a Tank Reactor 123
3.6.1 Overall Yield and Overall Selectivity 124
3.6.2 Parallel Reactions 125
3.6.3 Consecutive Reactions 129
3.7 Semibatch Tank Reactor 133
3.8 Nonisothermal Batch Reactor 138
3.9 Steady-State Operation of CSTR 145
3.9.1 Heat Balance for CSTR 145
3.9.2 Steady-States of CSTR 147
Summary 151
Further Reading 152
Problems 153
4. Tubular Reactor 161
4.1 Plug Flow 161
4.2 Design of Isothermal Tubular Reactor 163
4.2.1 Single Reaction 164
4.2.2 Multiple Reactions 168
4.2.3 Pseudo Homogeneous Model 176
4.3 Comparison of Reactor Volumes of Tubular and Tank Reactors 178
4.4 Recycle Reactor 184
4.5 Nonisothermal Tubular Reactor 185
4.5.1 Heat Balance Equation for Tubular Reactor 186
4.5.2 Adiabatic Tubular Reactor 188
4.5.3 Nonadiabatic Nonisothermal Tubular Reactor 193
4.6 Optimal Temperature Sequence for Tubular Reactors 197
4.6.1 Single Reaction 198
4.6.2 Multiple Reactions 200
Further Reading 203
Problems 203
5. Residence Time Distribution and Flow Models for Reactors 213
5.1 Residence Time Distribution 214
5.1.1 Overview 214
5.1.2 Quantitative Delineation of RTD 215
5.2 Experimental Determination of RTD 218
5.2.1 Pulse Experiments 219
5.2.2 Step Experiments 221
5.3 Statistical Eigenvalues of RTD 224
5.4 RTD of Ideal Reactors 228
5.4.1 Plug-Flow Model 228
5.4.2 Perfectly-Mixed Flow Model 230
5.5 Nonideal Flow Phenomenon 234
5.6 Nonideal Flow Models 238
5.6.1 Segregation Model 238
5.6.2 Tanks-in-Series Model 242
5.6.3 Axial Dispersion Model 247
5.7 Design of Nonideal Reactors 251
5.8 Mixing of Fluids in Flow Reactors 256
Further Reading 260
Problems 261
6. Chemical Reaction and Transport Phenomena in Heterogeneous System 265
6.1 Steps in Heterogeneous Reactions 266
6.1.1 Macroscopic Structures and Properties of Solid Catalyst Particles 266
6.1.2 Steps in a Catalytic Reaction 269
6.2 Heat and Mass Transfer Between Bulk Fluid and the Catalyst External Surface 270
6.2.1 Transport Coefficient 270
6.2.2 Concentration and Temperature Difference Between the External Surface of Catalyst and Bulk Fluid 272
6.2.3 Effect of External Diffusion on Heterogeneous Catalytic Reactions 275
6.3 Gas Diffusion in Porous Media 279
6.3.1 Diffusion in Pores 279
6.3.2 Diffusion in Porous Particles 280
6.4 Diffusion and Reaction in Porous Catalysts 281
6.4.1 Reactant Concentration Profile in Porous Catalysts 282
6.4.2 Internal Effectiveness Factor 285
6.4.3 Internal Effectiveness Factor for Non-first Order Reactions 290
6.4.4 Effectiveness Factor Under the Influences of Both Internal and External Diffusions 292
6.5 Effect of Internal Diffusion on Selectivity of Multiple Reactions 294
6.6 Determination of Diffusion Impact on Heterogeneous Reactions 297
6.6.1 Determination of the Effects of External Diffusion 297
6.6.2 Determining the Effects of Internal Diffusion 299
6.7 Effects of Diffusion on Experimental Measurement of Reaction Rate 301
Further Reading 305
Problems 306
展開全部
REACTION ENGINEERING(反應工程) 作者簡介
辛峰，天津大學 化工學院，系主任，教授（博士生導師）， 講授的主要課程 ①、本科生必修課《化學反應工程》； ②、碩士生學位課《化學反應工程Ⅱ》； ③、博士生學位課《高等反應工程》； ④、博士生學位課《化學工程前沿》； ⑤、本科生必修課《計算機應用基礎》。 主編教材 ①、主編天津市“十五”規劃重點教材《反應工程基礎》，2001-2005； ②、主編全國工程碩士研究生教育核心教材《反應器的設計與強化》，2004-。 出版教材 ①、化學工程實驗，化學工業出版社，1996，參編； ②、化學反應工程習題精解，科學出版社，2003年，第二作者。 主持的教學研究課題 ①、國家精品課程、天津市精品課程、天津大學精品課程《反應工程》； ②、獲2003年度天津大學教學研究成果一等獎一項； ③、“新世紀高等教育教學改革工程”-“世行貸款21世紀初高等教育教學改革項目”《化工類專業創新人才培養模式、教學內容、教學方法和教學技術改革的研究與實踐》項目的子項目《探索適宜培養創新人才的“化學反應工程”教學內容、方法與輔助教學技術》，子項目負責人； ④、天津大學“面向21世紀教育振興行動計劃”重點項目“反應工程課程建設”項目負責人； ⑤、天津大學“十五規劃”課程-反應工程，項目負責人。 科研 ①、負責國家自然科學基金“多孔介質結構表征及內擴散機理的研究” 和“超細鈦硅分子篩環己酮漿態氨肟化反應動力學分析”； ②、負責中石化總公司技術開發中心發展基金“環己烷生產中反應和精餾耦合技術的開發”； ③、負責天津市自然科學基金“外場促進微乳化柴油的形成及燃燒過程分析”，“超臨界條件下丙烷芳構化反應的研究”； ④、負責中石化巴陵分公司“羥氨反應系統改造研究及設計”等。
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